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1 Landolt-Börnstein / New Series

2 Landolt-Börnstein Numerical Data and Functional Relationships in Science and Technology New Series Editor in Chief: W. Martienssen Units and Fundamental Constants in Physics and Chemistry Elementary Particles, Nuclei and Atoms (Group I) (Formerly: Nuclear and Particle Physics) Molecules and Radicals (Group II) (Formerly: Atomic and Molecular Physics) Condensed Matter (Group III) (Formerly: Solid State Physics) Physical Chemistry (Group IV) (Formerly: Macroscopic Properties of Matter) Geophysics (Group V) Astronomy and Astrophysics (Group VI) Biophysics (Group VII) Advanced Materials and Technologies (Group VIII) Some of the group names have been changed to provide a better description of their contents.

3 Landolt-Börnstein Numerical Data and Functional Relationships in Science and Technology New Series / Editor in Chief: W. Martienssen Group III: Condensed Matter Volume 44 Semiconductors Subvolume A: New Data and Updates for I-VII, III-V, III-VI and IV-VI Compounds Editor: U. Rössler Authors: T. Dietl, W. Dobrowolski, E.C. Fernandes da Silva, B. Hönerlage, B.K. Meyer, U. Rössler, T. Story

4 ISSN (Condensed Matter) ISBN Springer Berlin Heidelberg New York e-isbn Library of Congress Cataloging in Publication Data Zahlenwerte und Funktionen aus Naturwissenschaften und Technik, Neue Serie Editor in Chief: W. Martienssen Vol. III/44A: Editor: U. Rössler At head of title: Landolt-Börnstein. Added t.p.: Numerical data and functional relationships in science and technology. Tables chiefly in English. Intended to supersede the Physikalisch-chemische Tabellen by H. Landolt and R. Börnstein of which the 6th ed. began publication in 1950 under title: Zahlenwerte und Funktionen aus Physik, Chemie, Astronomie, Geophysik und Technik. Vols. published after v. 1 of group I have imprint: Berlin, New York, Springer-Verlag Includes bibliographies. 1. Physics Tables. 2. Chemistry Tables. 3. Engineering Tables. I. Börnstein, R. (Richard), II. Landolt, H. (Hans), III. Physikalisch-chemische Tabellen. IV. Title: Numerical data and functional relationships in science and technology. QC ' This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in other ways, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer-Verlag. Violations are liable for prosecution act under German Copyright Law. Springer is a part of Springer Science+Business Media springeronline.com Springer-Verlag Berlin Heidelberg 2008 Printed in Germany The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Product Liability: The data and other information in this handbook have been carefully extracted and evaluated by experts from the original literature. Furthermore, they have been checked for correctness by authors and the editorial staff before printing. Nevertheless, the publisher can give no guarantee for the correctness of the data and information provided. In any individual case of application, the respective user must check the correctness by consulting other relevant sources of information. Cover layout: Erich Kirchner, Heidelberg Typesetting: Authors and Redaktion Landolt-Börnstein, Darmstadt Printing and Binding: AZ Druck, Kempten SPIN: / Printed on acid-free paper

5 Preface of the editor The last update of the Landolt-Börnstein New Series on semiconductor physics and technology, consisting of the five subvolumes III/41A to III/41E, was published in the years between 1998 and Instead of a revised edition of the previous volumes III/17A to III/17I (published between 1982 and 1985) and the supplementary volumes III/22A and III/22B (published between 1987 and 1989) or a new supplement, this last update followed a new concept of providing a CD-ROM of each subvolume with all updates and a revised version of the corresponding old data besides the printed version of the new data. Thus, all collected data was made available to the user in a very compact and consistent form. In the more than five years since this last update, the field of semiconductor research has continuously grown. Both new data of standard semiconductors and, even more, data on a variety of new materials have been published. In the meantime, the publisher had decided to develop the Landolt-Börnstein data collection into an electronic major reference work. Therefore, the Springer Verlag decided in 2005 to start a new update project with the intention to complete the online database in an almost continuous way. The first input, containing data on semiconductors with tetrahedral coordination of the I-VII, II-VI and III-V, III- VI and IV-VI compound families, will go online in 2008 and also appear in printed form as two subvolumes III/44A and III/41B. Further data shall follow on a short time scale. The contents of the two printed subvolumes are: Subvolume III/44A: (mspace) New Data and Updates for I-VII, III-V, III-VI and IV-VI Compounds; Subvolume III/44B: (mspace) New Data and Updates for II-VI Compounds. The first subvolume III/44A contains a Systematics of Semiconductor Properties, which should help the non-specialist user to understand the meaning of the material parameters. The documents of both subvolumes, including links to older material and to the original citations, will be available on where also the Landolt-Börnstein e-catalog and a User Guide describing different ways of accessing the electronic data of Landolt-Börnstein are presented. These two subvolumes would not have been accomplished without the diligence and patience of the authors, whose efforts and expertise have to be acknowledged in the first place. Every single page and document had to pass the visual control of Tobias Schwaibold of the Landolt-Börnstein editorial office several times. Dr. Rainer Poerschke contributed much to the project by his coordination and encouraging guidance. I am grateful to both of them for their cooperation. Regensburg, February 2008 The Editor

6 Editor U. Rössler Institut für Theoretische Physik Universitaet Regensburg Regensburg, Germany Authors T. Dietl Laboratory for Cryogenic and Spintronic Research Institute of Physics, Polish Academy of Sciences al. Lotnikow 32/46, Warszawa, POLAND W. Dobrowolski Laboratory for Cryogenic and Spintronic Research Institute of Physics, Polish Academy of Sciences al. Lotnikow 32/46, Warszawa, POLAND E.C. Fernandes da Silva Instituto de Fisica Laboratorio de Novos Materiais Semicondutores Universidade de Sao Paulo Rua do Matao, travessa R, Butanta, Sao Paulo, SP, Brasil B. Hönerlage IPCMS/GONLO, BP 43 23, rue du Loess Strasbourg cedex 2, France B.K. Meyer 1. Physikalisches Institut Universitaet Giessen Heinrich-Buff-Ring Giessen, Germany U. Rössler Institut für Theoretische Physik Universitaet Regensburg Regensburg, Germany

7 T. Story Laboratory for Cryogenic and Spintronic Research Institute of Physics, Polish Academy of Sciences al. Lotnikow 32/46, Warszawa, POLAND Landolt-Börnstein: Editorial Office Gagernstr. 8, D Darmstadt, Germany fax: +49 (6151) Internet:

8 Contents III/44A Semiconductors: New Data and Updates for I-VII, III-V, III-VI and IV-VI Compounds Systematics of Semiconductor Data Structural Properties..... X 2. Thermal and Thermodynamic Properties....X 3. Electronic Properties..... X 4. Impurities and Defects.... X 5. Lattice Properties...X 6. Transport Properties..... X 7. Optical Properties...X 8. Magnetic Properties..... X 9. References...X Index of Substances...X List of Symbols...X Conversion Factors...X Data for I-VII, III-V, III-VI and IV-VI Compounds (sorted by element system)...x

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