Landolt-Börnstein Numerical Data and Functional Relationships in Science and Technology New Series / Editor in Chief: W. Martienssen Group IV: Physical Chemistry Volume 12 Phase Equilibria, Crystallographic and Thermodynamic Data of Binary Alloys Subvolume A Ac Ag... Au Zr Supplement to Subvolume IV/5A Editor and Author: B. Predel with technical cooperation of Felicitas Predel
ISSN 1615-2018 (Physical Chemistry) ISBN-10 ISBN-13 3-540-43534-4 Springer Berlin Heidelberg New York 978-3-540-43534-1 Springer Berlin Heidelberg New York Library of Congress Cataloging in Publication Data Zahlenwerte und Funktionen aus Naturwissenschaften und Technik, Neue Serie Editor in Chief: W. Martienssen Vol. IV/12: Editor: B. Predel At head of title: Landolt-Börnstein. Added t.p.: Numerical data and functional relationships in science and technology. Tables chiefly in English. Intended to supersede the Physikalisch-chemische Tabellen by H. Landolt and R. Börnstein of which the 6th ed. began publication in 1950 under title: Zahlenwerte und Funktionen aus Physik, Chemie, Astronomie, Geophysik und Technik. Vols. published after v. 1 of group I have imprint: Berlin, New York, Springer-Verlag Includes bibliographies. 1. Physics--Tables. 2. Chemistry--Tables. 3. Engineering--Tables. I. Börnstein, R. (Richard), 1852-1913. II. Landolt, H. (Hans), 1831-1910. III. Physikalisch-chemische Tabellen. IV. Title: Numerical data and functional relationships in science and technology. QC61.23 502'.12 62-53136 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in other ways, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer-Verlag. Violations are liable for prosecution act under German Copyright Law. Springer is a part of Springer Science+Business Media springeronline.com Springer-Verlag Berlin Heidelberg 2006 Printed in Germany The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Product Liability: The data and other information in this handbook have been carefully extracted and evaluated by experts from the original literature. Furthermore, they have been checked for correctness by authors and the editorial staff before printing. Nevertheless, the publisher can give no guarantee for the correctness of the data and information provided. In any individual case of application, the respective user must check the correctness by consulting other relevant sources of information. Cover layout: Erich Kirchner, Heidelberg Typesetting: Authors and Redaktion Landolt-Börnstein, Darmstadt Printing and binding: AZ-Druck, Kempten SPIN: 1079 3176 63/3020-5 4 3 2 1 0 Printed on acid-free paper
Editor and Author with technical cooperation of Felicitas Predel B. Predel Director em. of the Max-Planck-Institut für Metallforschung Seestraße 92 D-70174 Stuttgart, Germany Editorial Office Gagernstr. 8, D-64283 Darmstadt, Germany fax: +49 (6151) 171760 e-mail: Redaktion.Landolt-Boernstein@springer.com Internet http://www.landolt-boernstein.com/
Preface The first volume of this series has been issued in 1991. Since that time a remarkable progress in the knowledge of phase equilibria, of thermodynamic properties in general as well as of crystal structure of binary alloys has been obtained. This was realized to such an extend that now it should be possible and necessary to compile crtitically this quantity in supplement volumes. As hitherto, the text should be kept concise. Literature (up to about 1990) should only be mentioned, if it is most essential to clarify the new data or to close a gap of information. Stuttgart, January 2006 The Editor Acknowledgement The author likes to thank his family for its patience and kind consideration, but in particular he wants to express his gratitude to his daughter, Felicitas Predel, for her untiring efforts surveying the extensive literature and on typing as well as on proofreading of the manuscript.
Contents Introduction... XI Thermodynamic functions and notation used... XII Some physical properties of the elements.... XIV Crystal structures of the elements.... XVII Allotropic modifications of elements at normal pressure.... XIX High-pressure modifications of elements... XXII Some thermodynamic properties of the elements... XXV Enthalpies of transition of elements in the solid state... XXVII List of symbols... XXVIII List of abbreviations... XXX 97 Ac X binary systems... 1 Ac Ag... 1 Ac Au... 1 Ac B... 2 Ac Cr... 2 Ac Cu... 3 Ac H... 3 Ac Hg... 3 Ac Mg... 4 Ac O... 4 Ac S... 4 98 Ag X binary systems... 5 Ag Al... 5 Ag Ar... 9 Ag As... 9 Ag At... 10 Ag Au... 10 Ag B... 11 Ag Ba... 11 Ag Bi... 12 Ag C... 15 Ag Ca... 15 Ag Ce... 17 Ag Cl... 19 Ag Cu... 19 Ag Dy... 24 Ag Eu... 24 Ag F... 25 Ag Fr... 25 Ag Ga... 26 Ag Gd... 27 Ag Ge... 28 Ag H... 29 Ag He... 32 Ag Hf... 32 Ag Hg... 33 Ag I... 35 Ag In... 36 Ag Ir... 36 Ag La... 37 Ag Lu... 39 Ag Mg... 40 Ag Mn... 41 Ag Mo... 41 Ag Nd... 42 Ag P... 44 Ag Pa... 47 Ag Pm... 47 Ag Po... 48 Ag Pr... 49 Ag Pt... 49 Ag Ra... 50
VIII Contents Ag Re... 51 Ag Rn... 52 Ag Ru... 52 Ag Sb... 53 Ag Sc... 54 Ag Se... 54 Ag Sm... 56 Ag Sn... 57 Ag Ta... 59 Ag Tc... 60 Ag Te... 60 Ag Th... 62 Ag Ti... 62 Ag Tm... 63 Ag V... 64 Ag W... 65 Ag Xe... 66 Ag Y... 66 Ag Yb... 67 Ag Zn... 67 Ag Zr... 70 99 Al X binary systems... 71 Al Au... 71 Al B... 72 Al Ba... 74 Al C... 77 Al Ca... 81 Al Ce... 84 Al Co... 85 Al Cr... 87 Al Cs... 90 Al Cu... 91 Al Eu... 93 Al Fe... 94 Al Ga... 95 Al Gd... 96 Al Ge... 97 Al H... 100 Al Hf... 102 Al In... 104 Al Ir... 104 Al La... 105 Al Li... 108 Al Lu... 110 Al Mg... 111 Al Mn... 115 Al Mo... 121 Al Nb... 123 Al Nd... 123 Al Ni... 125 Al O... 129 Al Os... 130 Al Pb... 131 Al Pd... 131 Al Pm... 132 Al Pr... 133 Al Pt... 134 Al Rb... 136 Al Re... 136 Al Rh... 138 Al Ru... 139 Al S... 140 Al Sb... 140 Al Sc... 142 Al Se... 144 Al Si... 144 Al Sm... 146 Al Sn... 146 Al Sr... 147 Al Ta... 150 Al Tb... 151 Al Tc... 152 Al Te... 152 Al Ti... 154 Al Tl... 165 Al Tm... 166 Al U... 166 Al V... 168 Al W... 168 Al Y... 168 Al Yb... 170 Al Zn... 170 Al Zr... 172 100 Am X binary systems... 175 Am As... 175 Am Be... 175 Am Bi... 176 Am Cu... 176 Am H... 176 Am Hg... 177 Am P... 180 Am Pd... 180 Am Pt... 181 Am Pu... 182 Am S... 184 Am Sb... 184 Am N... 177 Am Np... 177
Contents IX Am O... 179 Am Te... 185 Am U... 185 101 Ar X binary systems... 187 Ar Au... 187 Ar Mg... 188 Ar Be... 187 102 As X binary systems... 189 As B... 189 As Ba... 190 As Bk... 190 As Ca... 191 As Cd... 191 As Cf... 193 As Cm... 194 As Co... 194 As Cr... 195 As Cs... 197 As Cu... 198 As Dy... 201 As Er... 202 As Eu... 203 As Fe... 204 As Ga... 208 As Gd... 209 As Ge... 210 As Hf... 210 As Hg... 211 As Ho... 211 As In... 212 As Ir... 213 As K... 214 As Li... 215 As Lu... 216 As Mn... 216 As Na... 218 As Np... 219 As O... 219 As Os... 220 As P... 221 As Pb... 221 As Pd... 222 As Pt... 224 As Rb... 225 As S... 226 As Sc... 228 As Se... 228 As Si... 230 As Sm... 230 As Sn... 231 As Sr... 233 As Tb... 234 As Tc... 235 As Te... 235 As Th... 236 As Ti... 236 As Tm... 237 As V... 238 As Yb... 239 As Zn... 240 As Zr... 243 103 At X binary systems... 244 At Au... 244 At Mo... 244 At Hg... 244 104 Au X binary systems... 246 Au B... 246 Au Ba... 247 Au Be... 248 Au Ca... 249 Au Ce... 250 Au Er... 252 Au F... 254 Au Fr... 255 Au Ga... 255 Au Gd... 256 Au Ge... 257 Au Hf... 258 Au Hg... 259 Au Ho... 260 Au I... 261 Au In... 261 Au K... 262 Au Kr... 263
X Contents Au La... 263 Au Lu... 264 Au Na... 265 Au Nb... 266 Au Nd... 266 Au Ni... 269 Au O... 272 Au Pb... 272 Au Pm... 273 Au Po... 274 Au Pr... 274 Au Pt... 276 Au Ra... 276 Au Rb... 277 Au Rn... 277 Au Sb... 278 Au Sc... 280 Au Si... 282 Au Sn... 282 Au Ta... 283 Au Tb... 285 Au Te... 286 Au Ti... 287 Au Tm... 288 Au V... 289 Au Xe... 289 Au Y... 290 Au Zn... 290 Au Zr... 292 Index of substances for subvolumes IV/12A and IV/5... 295