Recycling of Liquid Crystal Displays for Maximum Resource Recovery

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Recycling of Liquid Crystal Displays for Maximum Resource Recovery Fu Zhao, Ph.D. Associate Professor School of Mechanical Engineering Division of Environmental and Ecological Engineering Purdue University

Market share of TVs by technology (million units) DisplaySearch, Quarterly Advanced Global TV Shipment and Forecast Report, Q2, 2010.

Issues with CRTs http://www.surreyleader.com/news/200097481.html Also, check Unwanted Electronic Gear Rising in Toxic Piles, NY Times, 03/19/2013

Recycling LCDs cost effectively is a glaring industrial need

Status of e-waste regulation in US Source: Electronics Take Back Coalition Landfill is not longer an option

Potential value streams of an LCD monitor Average Weight (lb) Market Value ($/lb) Recovery Value ($) Steel 2.88 0.79 2.26 Mixed plastics 3.70 0.19 0.68 Wire and cable 0.06 0.93 0.05 Screen driver circuit* 0.19 6.56 1.25 Other circuit boards* 0.74 4.28 3.19 Backlight lamps 2-4 pieces -$0.40/piece -1.20 Recovery value total $6.23 Note: These estimates were made in October 2012 when gold price was at its high At recyclers, labor rate and overhead vary (we have seen as low as $20 and as high as $60/hour).

Apparently you want to do it as quick as possible, but: You don t want to break the CCFL backlights (to avoid mercury contamination) No shredding! The backlights are hidden deep in the assembly. Different monitors have different designs, different screws, etc. (even opening the case could be challenging!) Liquid crystals present additional challenges.

Custom Tool and Disassembling Process Step 1: open outer casing

Oscillating Cutter

Step 2: Exposing screen assembly and circuit boards Wire cutter Power screwdriver

Step 3: Detaching Circuit Boards

Step 4: Opening screen assembly

Step 5: Remove liquid crystal A paper cutter works just fine Solvents tested for LC removal: Ethanol, Methanol, Acetone, Toluene, Hexane

Should we recover Indium or ITO?

It can be done in about 4 minutes and this is before optimization. LCD TVs can be disassembled in a similar way but their backlights are not well protected.

Team at the National Sustainable Design Expo

As we didn t make to the EPA P3 Phase II (we received an honorable mention) we are looking for other opportunities. However, if you are interested in this work and believe you are at a better position to pursue it further we d happy to provide all the materials we have. Simply send an email to: fzhao@purdue.edu

An interesting question from the judges at the competition: Could your tools handle Apple products? Well, they are not designed for disassembly

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Insert Molding Insert molding is the manufacturing process in which a resin is fed into a heated barrel, mixed, and forced into a preconfigured mold cavity around a pre-placed insert where it cools and hardens. Inserts can be made of metals or different types of plastics which can help strengthen components and reduce the cost of production and waste. This becomes recyclers nightmare

NSF IGERT: Sustainable Electronics

Acknowledgements EPA P3 Team: Prof. Carol Handwerker, MSE/EEE Dave Zelinka, EEE Alyssa Martin, EEE Gamini Mendis, MSE Jili Liu, ME Sagar Sinha, ME Adam Lagro, ME Mike Owen, Management US EPA School of Mechanical Engineering, Purdue University Division of Environmental and Ecological Engineering, Purdue University Dynamic Recycling Inc. Recycle Force