(51) Int Cl.: C09K 11/59 ( ) C09K 11/64 ( ) C09K 11/80 ( )

Transcription

1 (19) TEPZZ_9Z Z88B_T (11) EP B1 (12) EUROPEAN PATENT SPECIFICATION (4) Date of publication and mention of the grant of the patent: Bulletin 13/09 (1) Int Cl.: C09K 11/9 (06.01) C09K 11/64 (06.01) C09K 11/80 (06.01) (21) Application number: (22) Date of filing: (4) Green Phosphor and Plasma Display Panel Including the Same Grüner Leuchtstoff und diesen enthaltende Plasmaanzeigevorrichtung Luminophore vert et écran à plasma le comprenant (84) Designated Contracting States: DE FR GB HU () Priority: KR KR (43) Date of publication of application: Bulletin 08/13 (73) Proprietor: Samsung SDI Co., Ltd. Gyeonggi-do (KR) (72) Inventors: Lee, Soon-Rewl Yeongtong-gu, Suwon-si, Gyeonggi-do (KR) Lee, Sung-Yong Yeongtong-gu, Suwon-si, Gyeonggi-do, (KR) Yoo, Young-Gil Yeongtong-gu, Suwon-si, Gyeonggi-do (KR) Kim, Jin-Won Yeongtong-gu, Suwon-si, Gyeonggi-do, (KR) Kim, Young-Kwan, Yongin-si, Gyeonggi-do, (KP) (74) Representative: Killin, Stephen James Venner Shipley LLP 0 Aldersgate London EC1A 4HD (GB) (6) References cited: EP-A WO-A-0/0121 US-A US-A US-B DATABASE WPI Week 04 Thomson Scientific, London, GB; AN XP & JP A (SUMITOMO CHEM CO LTD) 14 July 0 ( ) & JP A (SUMITOMO CHEMICAL CO) 14 July 0 ( ) NOBUYUKI YOKOSAWA, KIYOSHI SUZUKI, EIICHIRO NAKAZAWA: "Vacuum Ultraviolet Excitation Processes of YAl3(BO3)4:R (R = Eu3+, Gd3+ and Tb3+)" JPN. J. APPL. PHYS., vol. 42, September 03 (03-09), pages 66-69, XP EP B1 Note: Within nine months of the publication of the mention of the grant of the European patent in the European Patent Bulletin, any person may give notice to the European Patent Office of opposition to that patent, in accordance with the Implementing Regulations. Notice of opposition shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention). Printed by Jouve, 7001 PARIS (FR)

2 Description 2 3 [0001] The present embodiments relate to a green phosphor for a plasma display panel (PDP) and a PDP including a phosphor layer formed of the same, and more particularly, to a green phosphor for a PDP having an improved luminance saturation characteristic and a PDP including a phosphor layer formed of the green phosphor. [0002] Phosphors emit light when they are exposed to energy. In general, phosphors are used in light sources such as mercury fluorescent lamps and mercury free fluorescent lamps, electron emission devices, plasma display panels (PDPs), etc. In the future, phosphors may be used for a wider range of applications as new multimedia devices are developed. [0003] PDPs are flat panel displays that display images using light emitted by ultraviolet rays that are created by discharge of a mixture of gases including neon and xenon injected into an area between a pair of glass substrates. Visible light is created by each phosphor using resonance radiation light of xenon ion (147 nm vacuum ultraviolet rays). [0004] JP discloses a fluorescent material containing fluorescent material (A) containing terbium as an activator to complex oxide of formula M 1 2 O 3 -mal 2 O 3 -nb 2 O 3 and a fluorescent material (B) containing silicate which contains manganese as an activator. [000] EP16414 discloses a plasma display device provided with a green color phosphor which is any one of or a combination of two or more phosphors selected from compounds defined by the general formula M 1-x Al 12 O 19 :Mn x (where "M" denotes one of Ca, Sr, Eu and Zn) having a magnetoplumbite crystal structure, (Y 1-a-y Gd a )(Ga t-x Al x ) 3 (BO 3 ) 4 :Tby, (Y 1-a-y Gda)(Ga 1-x Al x ) 3 (BO 3 ) 4 :Ce y, Tby, (Y 1-a-y Gd a ) BO 3 ) 4 :Tb y and (Y 1-a-y Gd a ) 3 (Ga 1-x Al) O 12 :Tb y having any of an yttrium borate crystal structure and yttrium aluminate crystal structure. [0006] ZnSi 2 O 4 :Mn (ZSM) has been widely used as a green phosphor for PDPs, and ZSM has also been used as a main constituent of a green phosphor for PDPs in combination with YBO 3 :Tb (YBT) and (Ba,Sr,Mg)O αal 2 O 3 :Mn (BAM). [0007] ZSM phosphors have excellent luminance, but short lifetime. Further, the surface of ZSM phosphors has a high negative polarity, thus resulting in a high discharge voltage. YBT phosphors have excellent luminance, long lifetime, and reduced discharge voltage, but poor color purity. BAM phosphors have excellent color purity and reduced discharge voltage, but short lifetime and long decay time. [0008] ZSM phosphors can be used either alone or in combination with other phosphors to prepare a green phosphor layer for a PDP. Usually, ZSM is used alone, or as a main phosphor in combination with YBT and/or BAM. However, ZSM has luminance saturation. That is, luminance per unit sustain pulse is saturated as the number of sustain pulses increases, and a peak luminance which is a main property of PDPs decreases, and thus bright room contrast decreases. [0009] Luminance saturation is an important factor determining gray-level and image quality. Thus, the development of a phosphor having long lifetime and excellent luminance without luminance saturation is urgently required. [00] The present invention provides a green phosphor for a plasma display panel (PDP) having excellent luminance, long lifetime, and an improved luminance saturation characteristic. [0011] The present invention also provides a PDP including a phosphor layer formed of the green phosphor having excellent luminance, long lifetime, and an improved luminance saturation characteristic. [0012] According to a first aspect of the present invention, there is provided a green phosphor for a PDP comprising: a first phosphor represented by Formula 1; and a second phosphor including a phosphor represented by Formula 2 and a phosphor represented by Formula 3: Formula 1 Y 1-y Al 3 (BO 3 ) 4 :Tb y 4 Formula 2 Formula 3 Zn 2 SiO 4 :Mn (Ba,Sr,Mg)O αal 2 O 3 :Mn where o<y<1 and a is an integer of from 1 to [0013] According to a second aspect of the present invention, there is provided a PDP including: a transparent front substrate; a rear substrate which is parallel to the transparent front substrate; discharge cells defined by barrier ribs interposed between the transparent front substrate and the rear substrate; pairs of sustain electrodes extending in a first direction to correspond to the discharge cells, address electrodes extending in a second direction to cross the sustain electrodes and correspond to the discharge cells; a rear dielectric layer covering the address electrodes; red, green, and blue phosphor layers disposed inside the discharge cells; a front dielectric layer covering the pairs of sustain electrodes; and a discharge gas filled in the discharge cells, wherein the green phosphor layer is formed of a green phosphor according to the invention in its first aspect. [0014] According to a third aspect of the present invention, there is provided a plasma display panel comprising a 2

3 green phosphor according to the present invention in its first aspect. [00] According to a fourth aspect of the present invention, there is provided the use of a green phosphor according to the present invention in its first aspect in a plasma display panel. [0016] Further embodiments of the present invention in any of its various aspects are as described below or as defined in the sub-claims. [0017] The above and other features and advantages of the present embodiments will become more apparent by describing in detail exemplary embodiments thereof with reference to the attached drawings in which: FIGURE 1 is a perspective view illustrating a plasma display panel (PDP) according to an embodiment; FIGURE 2 is a graph illustrating the luminance saturation characteristic of a PDP including a phosphor layer formed of Zn 2 SiO 4 :Mn; FIGURE 3 is a graph illustrating the luminance saturation characteristic of a PDP including a phosphor layer formed of Y 1-y Al 3 (BO 3 ) 4 :Tb y ; and FIGURE 4 is a graph illustrating the luminance saturation characters of green phosphors according to Reference Examples 1 to 3 and Comparative Example [0018] In Formula 1, o<y<1, and preferably 0.4 y 0.6. [0019] The green phosphor of the current embodiment includes YAl 3 (BO 3 ) 4 having an excellent luminance saturation characteristic as a phosphor host and Tb as an activator, and the activated phosphor has an emission peak around nm. [00] The green phosphor for a PDP of Formula 1 is a green phosphor having an improved luminance saturation characteristic and increased peak luminance. [0021] ZnSi 2 O 4 :Mn (ZSM) phosphors are widely used as a green phosphor for PDPs. When ZSM phosphors are used, luminance saturation occurs, however a further increase of luminance does not occur even though the number of sustain pulses or the discharge intensity increases significantly. [0022] Luminance saturation is a phenomenon having non-uniform luminance in which unit luminance which is obtained from a pair of sustain pulses decreases as the number of sustain pulses increases at the same load condition. The unit luminance varies between small and large numbers of sustain discharges due to the luminance saturation. [0023] The green phosphor of the current embodiment has an improved luminance saturation characteristic, increased peak luminance, long lifetime and excellent discharge properties. [0024] Another aspect of the invention provides a green phosphor for a PDP including: a first phosphor represented by Formula 1; Formula 1 Y 1-y Al 3 (BO 3 ) 4 :Tb y where 0<y<1; and a second phosphor including a phosphor represented by Formula 2 and a phosphor represented by Formula 3. Formula 2 Zn 2 SiO 4 :Mn Formula 3 (Ba,Sr,Mg)O αal 2 O 3 :Mn 4 0 Here, α is an integer of from 1 to 23. [002] In the current embodiment, the first phosphor has greater luminance saturation characteristic and longer lifetime compared to conventional ZSM phosphors, and shorter decay time compared to YBO 3 :Tb (YBT) phosphors, and thus more effectively operates compared to those conventional phosphors. A phosphor having excellent color purity is used as the second phosphor. The phosphor of Formula 2 has excellent peak luminance and color purity and the phosphor of Formula 3 has excellent color purity. Thus, a PDP having improved image quality with excellent luminance and color purity and without luminance saturation can be manufactured by using the green phosphor including the first phosphor and the second phosphor according to the current embodiment. When the green phosphor for a PDP of the current embodiment is used, a PDP having improved peak luminance, shorter decay time, longer lifetime, and better discharge properties can be prepared compared to a PDP using conventional phosphors. [0026] The phosphor includes a first phosphor represented by Formula 1 and a second phosphor including a phosphor represented by Formula 2 and a phosphor represented by Formula 3. The amount of the second phosphor may be from about to about 0 parts by weight based on 0 parts by weight of the total amount of the first phosphor and the second phosphor. [0027] The second phosphor includes a phosphor represented by Formula 2 and a phosphor represented by Formula 3

4 The ratio of the phosphor of Formula 2 to the phosphor of Formula 3 may be in the range of about 2:1 to about 1:2. [0028] In another embodiment, the first phosphor is Y 0.,Al 3 (BO 3 ) 4 :Tb 0., and the second phosphor is Zn 2 SiO 4 :Mn and (Ba,Sr,Mg)O αal 2 O 3 :Mn where α is an integer of from to 7, and the ratio of Zn 2 SiO 4 :Mn to (Ba,Sr,Mg)O αal 2 O 3 : Mn may be from about 2:1 to 1:2. [0029] The phosphors of the present embodiments may be mixed with a binder, an organic solvent, etc. to obtain a paste composition, and then the paste composition can be printed, dried and sintered to form a phosphor layer. [00] A PDP including a phosphor layer formed of the green phosphor of the present embodiments, according to an embodiment will now be described in detail. [0031] The PDP according to the current embodiment includes: a transparent front substrate; a rear substrate which is parallel to the transparent front substrate; discharge cells defined by barrier ribs interposed between the transparent front substrate and the rear substrate; pairs of sustain electrodes extending in a first direction to correspond to the discharge cells; address electrodes extending in a second direction to cross the sustain electrodes and correspond to the discharge cells; a rear dielectric layer covering the address electrodes; red, green, and blue phosphor layers disposed inside the discharge cells; a front dielectric layer covering the pairs of sustain electrodes; and a discharge gas filled in the discharge cells, wherein the green phosphor includes a first phosphor represented by Formula 1 and a second phosphor including a phosphor represented by Formula 2 and a phosphor represented by Formula 3. [0032] A PDP including a phosphor layer formed of the green phosphor of the present embodiments, according to another embodiment will now be described in detail with reference to FIGURE 1. [0033] However, the PDP is not limited to the structure illustrated in FIGURE 1 and can have other structures. [0034] Referring to FIGURE 1, the PDP includes a front panel 2 and a rear panel 2. [003] The front panel 2 includes a front substrate 211, pairs of sustain electrodes 214 that are disposed on a rear surface of the front substrate 211 and extend in a first direction to correspond to the discharge cells, a front dielectric layer 2 covering the pairs of sustain electrodes 214, and a protective layer 216. [0036] The rear panel 2 includes a rear substrate 221 which is parallel to the front substrate 211, address electrodes 222 that are disposed on a front surface 221a of the rear substrate 221 and extend in a second direction perpendicular to the first direction to cross the pairs of sustain electrodes 214, a rear dielectric layer 223 covering the address electrodes 222, barrier ribs 224 that define a plurality of discharge cells 226 and are disposed between the front substrate 211 and the rear substrate 221, and more particularly on the rear dielectric layer 223, and a red phosphor layer 22a, a green phosphor layer 22b, and a blue phosphor layer 22c respectively formed of red, green, and blue phosphor that emit visible light by being excited by ultraviolet rays emitted from a discharge gas generated due to sustain discharges occurring in the discharge cells 226. [0037] According to an embodiment, the green phosphor layer 22b can be formed of a phosphor layer composition including a first phosphor of Formula 1 and a second phosphor including a phosphor represented by Formula 2 and a phosphor represented by Formula 3. [0038] To easily print a phosphor for a PDP according to the present embodiments, the phosphor can be mixed with a binder and a solvent to obtain a paste phase composition, and then the paste phase composition can be screen printed using a screen mesh. Then the printed composition can be dried and sintered to form a phosphor layer. [0039] The drying temperature of the printed composition may be from about 0 to about 0 C, and the sintering temperature may be from about to about 600 C, preferably about C, to remove organic materials of the paste phase composition. [00] The binder can be ethyl cellulose, and the amount of the binder may be in from about to about parts by weight based on 0 parts by weight of the phosphor. [0041] The solvent can be butyl carbitol (BCA) or terpineol, and the amount of the solvent may be from about 70 to about 0 parts by weight based on 0 parts by weight of the phosphor. [0042] The viscosity of the paste phase composition may be from about,000 to about 0,000 cps, and preferably about,000 cps. [0043] The phosphor layer composition according to the current embodiment can further include additives such as a dispersant, a plasticizer, an antioxidant, a leveler or the like, if necessary. In addition, all of the above additives are known to those of ordinary skill in the art and are commercially available. The amount of the additives may be from about 0.1 to about parts by weight based on a total amount of the phosphor layer composition. [0044] The red phosphor layer and the blue phosphor layer can be any red and blue phosphor layers that are conventionally used in the process of manufacturing a PDP. Examples of the red phosphor may include (Y,Gd)BO 3 :Eu, and Y(V,P)O 4 :Eu, and examples of the blue phosphor may include BaMgAl O 17 :Eu, and CaMgSi 2 O 6 :Eu. [004] The front substrate 211 and the rear substrate 221 can be formed of glass, for example. The front substrate 211 may have high light transmittance. [0046] The address electrodes 222 which are disposed on the front surface 221a of the rear substrate 221 and extend in the second direction to correspond to the discharge cells 226 may be formed of a metal having high electrical conductivity, such as Al. The address electrodes 222 are used together with a Y electrode 212 for an address discharge to 4

5 2 3 occur. The purpose of the address discharge is to select discharge cells 226 for emitting light. Once an address discharge has occurred in the discharge cells 226, a sustain discharge which will be described in detail can occur. [0047] The address electrodes 222 are covered by the rear dielectric layer 223, which prevents collision of the address electrodes 222 with charged particles that are generated during the address discharge, so that the address electrodes 222 can be protected. The rear dielectric layer 223 may be formed of a dielectric material capable of inducing discharged particles. The dielectric material can be, for example, PbO, B 2 O 3, SiO 2, or the like. [0048] The barrier ribs 224 defining the discharge cells 226 are interposed between the front substrate 211 and the rear substrate 221. The barrier ribs 224 secure a discharge space between the front substrate 211 and the rear substrate 221, prevent crosstalk between adjacent discharge cells 226, and enlarge the surface area of the phosphor layer 22. The barrier ribs 224 may be formed of, for example, a glass material including Pb, B, Si, Al, or O, and when required, the barrier ribs 224 may further include a filler, such as ZrO 2, TiO 2, and Al 2 O 3, and a pigment, such as Cr, Cu, Co, Fe, or TiO 2. [0049] The pairs of sustain electrodes 214 extend in the first direction, to correspond to the discharge cells 226, perpendicular to the second direction in which the address electrodes 222 extend. The pairs of sustain electrodes 214 include pairs of sustain electrodes 212 and 213. The pairs of sustain electrodes 214 are disposed parallel to each other at predetermined intervals on the front substrate 211. One of the sustain electrodes 213 is an X electrode and the other sustain electrode 212 is a Y electrode. The sustain discharge occurs due to a potential difference between the X electrode and the Y electrode. [000] The X electrode and the Y electrode include transparent electrodes 213b and 212b and bus electrodes 213a and 212a, respectively. In some cases, however, the bus electrodes 213a and 212a can be solely used to form a scanning electrode and a common electrode. [001] The transparent electrodes 213b and 212b may be formed of a conductive and transparent material, so that the light emitted from the phosphor can pass through the front substrate 211 without being blocked. The conductive and transparent material can be indium tin oxide (ITO). However, since the conductive and transparent material, such as ITO, has a high resistance, and when the sustain electrodes 214 are formed of the transparent electrodes 213b and 212b, the sustain electrodes 214 have a large voltage drop in a lengthwise direction of the transparent electrodes 213b and 212b, the power consumption of the PDP increases and the response speed of images reduces. In order to prevent these problems, the bus electrodes 213a and 212a are formed of a highly conductive metal, such as Ag, and are formed at outer edges of the transparent electrodes 213b and 212b. [002] The sustain electrodes 212 and 213 are covered by the front dielectric layer 2. The front dielectric layer 2 electrically insulates the X electrodes from the Y electrodes, and prevents collisions of charged particles with the sustain electrodes 212 and 213, so that the sustain electrodes 212 and 213 are protected. The front dielectric layer 2 is formed of a dielectric material having high light transmittance, such as PbO, B 2 O 3, or SiO 2. [003] The protective layer 216 can be formed on the front dielectric layer 2. The protective layer 216 prevents collisions of charged particles with the front dielectric layer 2 during the sustain discharge so that the front dielectric layer 2 can be protected, and generates many secondary electrons during the sustain discharge. The protective layer 216 may be formed of MgO, for example. [004] The discharge cells 226 are filled with a discharge gas. The discharge gas can be, for example a gaseous mixture of Ne and Xe in which the amount of Xe is from about to about %. When needed, a part of Ne can be replaced with He. [00] The present embodiments will be described in further detail with reference to the following examples. Reference Example [006] parts by weight of Y 0. Al 3 (BO 3 ) 4 :Tb 0., 0 parts by weight of butyl carbitol acetate and 8 parts by weight of ethyl cellulose were mixed. The mixture was mixed with a vehicle to prepare a green phosphor layer paste composition. The prepared green phosphor layer paste composition was screen printed in discharge cells of a PDP, dried, and then sintered to prepare a green phosphor layer. In the PDP, a discharge gas included 93% by volume of Ne and 7% by volume of Xe. Reference Example 2 [007] A green phosphor layer was prepared in the same manner as in Example 1, except that parts by weight of Y o. Al 3 (BO 3 ) 4 :Tb 0. and parts by weight of Zn 2 SiO 4 :Mn were used instead of parts by weight of Y 0. Al 3 (BO 3 ) 4 :Tb 0.. Reference Example 3 [008] A green phosphor layer was prepared in the same manner as in Example 1, except that that parts by weight

6 of Y 0. Al 3 (BO 3 ) 4 :Tb 0. and parts by weight of (Ba,Mg)OAl 2 O 3 :Mn were used instead of parts by weight of Y 0. Al 3 (BO 3 ) 4 :Tb 0.. Example 4 [009] A green phosphor layer was prepared in the same manner as in Example 1, except that that parts by weight of Y 0. Al 3 (BO 3 ) 4 :Tb 0., parts by weight of zn 2 SiO 4 :Mn and parts by weight of (Ba,Mg)OAl 2 O 3 :Mn were used instead of parts by weight of Y 0. Al 3 (BO 3 ) 4 :Tb 0.. Reference Example [0060] 6% by weight of ethylene cellulose was dissolved in 4% by weight of a mixed organic solvent having butyl carbitol acetate and terpineol (:70 by volume). % by weight of Y 0. Al 3 (BO 3 ) 4 :Tb 0. was added thereto and the mixture was stirred to prepare a green phosphor composition. The prepared green phosphor composition was coated on emission cells and sintered to prepare a PDP having a green phosphor layer. Reference Example 6 [0061] A green phosphor layer was prepared in the same manner as in Example 1, except that (Y 0.3 Gdo. 2 )Al 3 (BO 3 ) 4 : Tb 0. was used. Reference Example 7 2 [0062] A green phosphor layer was prepared in the same manner as in Example 1, except that Y 0. (Al,Ga) 3 (BO 3 ) 4 : Tb 0. was used. Comparative Example 1 [0063] A green phosphor layer was prepared in the same manner as in Example 1, except that 0% of Zn 2 SiO 4 :Mn was used instead of Y 0. Al 3 (BO 3 ) 4 :Tb 0.. Comparative Example 2 3 [0064] A green phosphor layer was prepared in the same manner as in Example 1, except that 0% of YBO 3 :Tb was used instead of Y 0. Al 3 (BO 3 ) 4 :Tb 0.. Comparative Example 3 [006] A green phosphor layer was prepared in the same manner as in Example 1, except that 0% of (Ba,Mg) OAl 2 O3:Mn was used instead of Y 0. Al 3 (BO 3 ) 4 :Tb 0.. Comparative Example 4 4 [0066] A green phosphor layer was prepared in the same manner as in Example, except that Zn 2 SiO 4 :Mn was used. Measurement and Result 0 [0067] Color purity, relative luminance, decay time, lifetime, luminance, and discharge voltage of the green phosphor layers prepared according to Reference Examples 1 to 3, Example 4 and Comparative Examples 1 to 3 were measured using devices and methods as follows. (1) color purity: device: CA0+, Minolta (2) relative luminance: device: CA0+, Minolta (3) decay time: time taken until luminance is reduced to 1/ (4) lifetime: luminance maintenance rate over a long period of time of aging panels, device: CA0+, Minolta () luminance saturation: luminance according to the number of sustain pulses, device: CA0+, Minolta (6) discharge voltage: opposed discharge voltage and VTC curve 6

7 [0068] The green phosphor layer using Y 0. Al 3 (BO 3 ) 4 :Tb 0. according to Reference Example 1 had similar luminance and color purity compared to using YBO 3 :Tb, and excellent discharge properties and long lifetime. [0069] The decay time of the green phosphor layer of Reference Example 1 was 6 ms. The decay times of the green phosphor layers of Comparative Example 1, Comparative Example 2, and Comparative Example 3 were in the ranges of 9 to ms, 12 to 14 ms, and 16 to 18 ms, respectively. [0070] The luminance saturation characteristics of the green phosphor layers according to Reference Examples 1 to 3 and Example 4 were excellent, being 90 to 9% in Reference Example 1, 73 to 87% in Reference Example 2, 82 to 90% in Reference Example 3, and 7 to 8% in Example 4. On the other hand, the luminance saturation characteristic of the green phosphor layer according to Comparative Example 1 was 60 to 6%. The luminance saturation characteristics of the green phosphor layers according to Comparative Example 2 and Comparative Example 3 were 90 to 9%, and 80 to 8%, respectively. [0071] FIGURE 3 is a graph illustrating the luminance saturation characteristic of the green phosphor layer according to Reference Example 1 and FIGURE 2 is a graph illustrating the luminance saturation characteristic of the green phosphor layer according to Comparative Example 1. [0072] Referring to FIGURE 3, the luminance saturation characteristic of the green phosphor layer according to Reference Example 1, that is, the green phosphor layer using Y 0. Al 3 (BO 3 ) 4 :Tb 0. was 91%, and referring to FIGURE 2, the luminance saturation characteristic of the green phosphor layer according to Comparative Example 1, that is, the green phosphor layer using ZnSi 2 O 4 :Mn was 71%. Thus, the green phosphor for a PDP according to Reference Example 1 has an excellent luminance saturation characteristic, and thus bright room contrast may increase. [0073] The measured properties of the green phosphors according to Reference Examples 1 to 3, Example 4 and Comparative Examples 1 to 3 are shown in Table Reference Example 1 Reference Example 2 Reference Example 3 Table 1 color purity luminance decaytime lifetime 3 s luminance saturation discharge voltage s s s s s s s Δ s s s s Example 4 s s s s s s Comparative Example 1 Comparative Example 2 Comparative Example 3 ( : excellent, s: good, Δ: fair, 3: poor) s s Δ s Δ Δ 3 3 s 4 0 [0074] As shown in Table 1, the green phosphor layer according to Reference Example 1 had poor color purity, but excellent properties in decay time, lifetime, luminance saturation, and discharge voltage. The green phosphor layers according to Reference Example 2Reference Example 3 and Example 4 had good properties in color purity, decay time, lifetime, luminance saturation, and discharge voltage. [007] The luminance of the green phosphor layers according to Reference Examples to 7 was measured based on 0% ofluminance of the green phosphor layer of Comparative Example 4. The results are shown in Table 2. Further, the luminance saturation characteristics of the green phosphor layers according to Reference Examples to 7 and Comparative Example 4 was measured based on 0% of the purest color which is a standard. The results are shown in Table 2. 7

8 Table 2 Relative luminance (%) Luminance saturation characteristic (%) Reference Example 9 86 Reference Example 6 92 Reference Example Comparative Example [0076] In addition, the luminance saturation characteristics of the green phosphor layers according to Reference Examples to 7 and Comparative Example 4 were measured according to the number of sustain pulses. The results are illustrated in FIGURE 4, and the standard luminance saturation value was also illustrated in FIGURE 4. As illustrated in FIGURE 4, the green phosphor layers of Reference Examples through 7 had closer luminance saturation to the standard saturation value compared to that of Comparative Example 4, and thus show pure color. [0077] The green phosphor for a PDP of the present embodiments has an improved luminance saturation characteristic, and can also be mixed with conventionally used green phosphors. Image quality can be improved according to a mixing rate of the green phosphor of the present embodiments and conventionally used green phosphors since color reproduction range widens and luminance does not decrease compared to using the conventional green phosphors. Claims 1. A green phosphor for a plasma display panel comprising: 2 a first phosphor represented by Formula 1; Formula 1: Y 1-y Al 3 (BO 3 ) 4 :Tb y and a second phosphor comprising a phosphor represented by Formula 2 and a phosphor represented by Formula 3: Formula 2 Zn 2 :SiO 4 :Mn 3 Formula 3 (Ba,Sr,Mg)O αalo 3 :Mn wherein 0<y<1 and α is an integer of from 1 to The green phosphor of claim 1, wherein the weight ratio of the phosphor of Formula 2 to the phosphor of Formula 3 is from 2:1 to 1:2. 3. The green phosphor of claims 1 or 2, wherein the first phosphor is Y 0. Al 3 (BO 3 ) 4 :Tb 0., and the second phosphor comprises Zn 2 SiO 4 :Mn and (Ba,Sr,Mg)O αal 2 O 3 :Mn where α is an integer of from to 7, and the weight ratio of the Zn 2 SiO 4 :Mn to (Ba,Sr,Mg)O αalo 3 :Mn is from 2:1 to 1: A plasma display panel comprising a green phosphor as claimed in any one of claims 1 to 3.. A plasma display panel according to claim 4 comprising: 0 a transparent front substrate; a rear substrate which is parallel to the transparent front substrate; discharge cells defined by barrier ribs interposed between the transparent front substrate and the rear substrate; pairs of sustain electrodes extending in a first direction to correspond to the discharge cells; address electrodes extending in a second direction to cross the sustain electrodes and correspond to the discharge cells; a rear dielectric layer covering the address electrodes; red, green, and blue phosphor layers disposed inside the discharge cells; a front dielectric layer covering the pairs of sustain electrodes; 8

9 and a discharge gas filled in the discharge cells, EP B1 wherein the green phosphor layer is formed of a green phosphor according to any one of claims 1 to Use of a green phosphor as claimed in any one of claims 1 to 3 in a plasma display panel. Patentansprüche 1. Grüner Phosphor für eine Plasmaanzeigetafel, umfassend: einen ersten Phosphor, dargestellt durch Formel 1; Formel 1: Y 1-y Al 3 (BO 3 ) 4 :Tb y und einen zweiten Phosphor, umfassend einen Phosphor, dargestellt durch Formel 2 und einen Phosphor, dargestellt durch Formel 3: Formel 2: Formel 3: Zn 2 SiO 4 :Mn (Ba,Sr,Mg)O αal 2 O 3 :Mn 2 wobei 0<y<1 und α eine ganze Zahl von 1 bis 23 ist. 2. Grüner Phosphor nach Anspruch 1, wobei das Gewichtsverhältnis des Phosphors von Formel 2 zu dem Phosphor von Formel 3 von 2:1 bis 1:2 ist. 3. Grüner Phosphor nach Anspruch 1 oder 2, wobei der erste Phosphor Y 0. Al 3 (BO 3 ) 4 :Tb 0. ist und der zweite Phosphor Zn 2 SiO 4 :Mn und (Ba,Sr,Mg)O αal 2 O 3 :Mn umfasst, wobei α eine ganze Zahl von bis 7 ist, und das Gewichtsverhältnis des Zn 2 SiO 4 :Mn zu (Ba,Sr,Mg)O αal 2 O 3 :Mn von 2:1 bis 1:2 ist. 4. Plasmaanzeigetafel, umfassend einen grünen Phosphor nach einem der Ansprüche 1 bis Plasmaanzeigetafel nach Anspruch 4, umfassend: 4 0 ein transparentes vorderes Substrat; ein hinteres Substrat parallel zu dem transparenten vorderen Substrat; Entladungszellen, die durch Sperrrippen definiert sind, die zwischen dem transparenten vorderen Substrat und dem hinteren Substrat eingesetzt sind; Paare von Sustain-Elektroden, die sich in eine erste Richtung erstrecken, um den Entladungszellen zu entsprechen; Adresselektroden, die sich in eine zweite Richtung erstrecken und die Sustain-Elektroden kreuzen und den Entladungszellen entsprechen; eine hintere dielektrische Schicht, die die Adresselektroden bedeckt; rote, grüne und blaue Phosphorschichten, die im Inneren der Entladungszellen angeordnet sind; eine vordere dielektrische Schicht, die die Paare von Sustain-Elektroden bedeckt; und ein Entladungsgas, das in die Entladungszellen gefüllt ist, wobei die grüne Phosphorschicht aus grünem Phosphor nach einem der Ansprüche 1 bis 3 gebildet ist. 6. Verwendung eines grünen Phosphors nach einem der Ansprüche 1 bis 3 in einer Plasmaanzeigetafel. Revendications 1. Luminophore vert destiné à un écran à plasma comprenant : un premier luminophore représenté par la formule 1 ; 9

10 la formule 1 : Y 1-y Al 3 (BO 3 ) 4 : Tb y et un deuxième luminophore comprenant un luminophore représenté par la formule 2 et un luminophore représenté par la formule 3 : la formule 2 Zn 2 SiO 4 : Mn la formule 3 (Ba, Sr, Mg)O αal 2 O 3 : Mn où 0 < y < 1 et α est un nombre entier allant de 1 à Luminophore vert de la revendication 1, où le rapport massique du luminophore répondant à la formule 2 sur le luminophore répondant à la formule 3 est de 2:1 à 1:2. 3. Luminophore vert de la revendication 1 ou 2, où le premier luminophore est Y 0, Al 3 (BO 3 ) 4 : Tb 0,, et le deuxième luminophore comprend Zn 2 SiO 4 : Mn et (Ba, Sr, Mg)O αal 2 O 3 : Mn, où α est un nombre entier allant de à 7, et le rapport massique du Zn 2 SiO 4 : Mn sur (Ba,Sr, Mg)O αal 2 O 3 : Mn est de 2:1 à 1:2. 4. Ecran à plasma comprenant un luminophore vert selon l une quelconque des revendications 1 à 3.. Ecran à plasma selon la revendication 4, comprenant : 2 3 un substrat avant transparent ; un substrat arrière qui est parallèle au substrat avant transparent ; des cellules de décharge définies par des nervures barrières interposées entre le substrat avant transparent et le substrat arrière ; des paires d électrodes d entretien s étendant dans une première direction pour correspondre aux cellules de décharge ; des électrodes d adresse s étendant dans une deuxième direction pour croiser les électrodes d entretien et correspondre aux cellules de décharge ; une couche diélectrique arrière recouvrant les électrodes d adresse ; des couches de luminophore rouge, vert, et bleu disposées à l intérieur des cellules de décharge ; une couche diélectrique avant recouvrant les paires d électrodes d entretien ; et un gaz de décharge rempli dans les cellules de décharge, où la couche de luminophore vert est réalisée en un luminophore vert selon l une quelconque des revendications 1 à Utilisation d un luminophore vert selon l une quelconque des revendications 1 à 3 dans un écran à plasma. 4 0

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15 REFERENCES CITED IN THE DESCRIPTION This list of references cited by the applicant is for the reader s convenience only. It does not form part of the European patent document. Even though great care has been taken in compiling the references, errors or omissions cannot be excluded and the EPO disclaims all liability in this regard. Patent documents cited in the description JP A [0004] EP A [000]