Mini-spectrometer. TF series. Compact and thin, built-in high-sensitivity CMOS image sensor for Raman spectroscopy C14214MA. Applications.

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TF series C14214MA Compact and thin, built-in high-sensitivity CMOS for Raman spectroscopy The mini-spectrometer TF series is a polychromator provided in a compact, thin case that houses optical elements,, and driver circuit. Spectrum data can be acquired by guiding measurement light into a mini-spectrometer through an optical fiber and transferring the measured results to a PC via the USB connection. The incorporation of a high-sensitivity CMOS maintains high sensitivity equivalent to that of a CCD and achieves low power consumption. Moreover, the trigger function that can be used for short-term integration enables spectroscopic measurement of pulse emissions. The product includes evaluation software with functions for setting measurement conditions, acquiring and saving data, drawing graphs, and so on. Furthermore, the DLL function specifications are disclosed, so users can create their original measurement software programs. Features Applications Raman spectroscopy Low stray light due to the adoption of a double grating, high spectral resolution.4 nm High-sensitivity CMOS built in (high sensitivity equivalent to that of a CCD) With trigger function High throughput using quartz transmission grating External power supply not necessary (USB bus powered) Easy installation in devices Stores wavelength conversion factor* 1 in internal memory *1: A conversion factor for converting the pixel number into a wavelength. A calculation factor for converting the A/D converted count into the input light level is not provided. Structure Parameter Specification Unit Dimensions (W D H) 1 6 12 mm Weight 95 g Image sensor High-sensitivity - Number of pixels 24 pixels Slit* 2 (H V) 1 4 μm NA* 3.11 - Connector for optical fiber SMA95 - *2: Input slit aperture size *3: Numeric aperture (solid angle) Absolute maximum ratings Parameter Value Unit Operating temperature* 4 +5 to +5 C Storage temperature* 4-2 to +7 C *4: No dew condensation When there is a temperature difference between a product and the surrounding area in high humidity environment, dew condensation may occur on the product surface. Dew condensation on the product may cause deterioration in characteristics and reliability. Note: Exceeding the absolute maximum ratings even momentarily may cause a drop in product quality. Always be sure to use the product within the absolute maximum ratings. www.hamamatsu.com 1

Optical characteristics Parameter Specification Unit Spectral response range 79 to 15 nm Spectral resolution Typ..4 (FWHM)* 5 Max..6 nm Wavelength reproducibility* 6 -.2 to +.2 nm Wavelength temperature dependence -.2 to +.2 nm/ C Spectral stray light* 5 * 7-33 max. db *5: When the slit in the table in Structure is used. The spectral resolution depends on the slit. *6: Measured under constant light input conditions *7: The ratio of the count measured when an 6 nm light is input to the count measured when an 6 ± 1 nm light is input Electrical characteristics Parameter Specification Unit A/D conversion 16 bit Integration time 11 to 1 μs Interface USB 2. - USB bus power current Typ. 22 consumption Max. 25 ma Spectral response (typical example) Spectral resolution vs. wavelength (typical example) 1 (Ta=25 C).6 (Ta=25 C) 9.5 Relative sensitivity (%) 7 6 5 4 3 Spectral resolution (nm).4.3.2 2 1.1 75 5 9 95 1 15 75 5 9 95 1 15 Wavelength (nm) Wavelength (nm) KACCB5EA KACCB51EA 2

A/D output Linearity (typical example) (Ta=25 C) 1 6 2 1 5 1 4 1 3 1 2 1 1 Typical example of A/D output Ideal A/D output -15 Difference between ideal value and typical example 1-2.1 1 1 1 15 1 5-5 -1 Difference between ideal value and typical example (%) A/D output (averaged over all pixels) Dark output vs. temperature (typical example) (Integration time=1 ms) 6 5 4 3 2 1 1 2 3 4 5 Integration time (ms) KACCB3EB Ambient temperature ( C) KACCB37EB A/D output is the output with dark output is subtracted when light is input. The difference between the ideal value and typical example contains a measurement error. The smaller the A/D output, the larger the measurement error. A/D output is the sum of the sensor and circuit offset outputs and the sensor dark output. Optical component layout The mini-spectrometer TF series employs a transmission holographic grating made of quartz and an optical system arranged on a robust optical base to produce high throughput and highly accurate optical characteristics. Focus lens Transmission grating Image sensor Input slit Collimating lens KACCC92EA 3

Connection example Spectrum data can be acquired by guiding measurement light into a mini-spectrometer through an optical fiber and transferring the measured results to a PC via the USB connection. Since there are no moving parts inside the device, constantly stable measurements can be expected. Moreover, the optical guiding section uses an optical fiber making connection to the measured object flexible. PC USB cable (accessory) Exciting LD light source Fiber Raman probe Measuring cell KACCC9EB Trigger operation modes In the C14214MA, the following trigger operation modes are available. You can switch between these modes from the evaluation software supplied with the C14214MA. (1) Asynchronous data measurement at software trigger input (2) Synchronous data measurement at software trigger input The first piece of digital data that is converted after a software trigger is applied from the PC is acquired. Sensor operation (integration) starts when a software trigger is applied from the PC. Software trigger Software trigger Software trigger Software trigger KACCC53EC KACCC55EB 4

(3) Asynchronous data measurement at external trigger input (4) Synchronous data measurement at external trigger input The first piece of digital data that is converted after an external trigger edge (rising or falling edge can be specified) is applied to the external trigger terminal is acquired. (for falling edge) Sensor operation (integration) starts when an external trigger edge (rising or falling edge can be specified) is applied to the external trigger terminal, and then the digital data is acquired. (for falling edge) KACCC56EA KACCC569EA (5) Asynchronous data measurement at external trigger input level (6) Synchronous data measurement at external trigger input level is acquired when an external trigger (high level or low level can be specified) is applied to the external trigger terminal. (for high level) KACCC54EB Sensor operation (integration) starts when a trigger (high level or low level can be specified) is applied to the external trigger terminal, and then the digital data is acquired. (for low level) KACCC56EB In any of the modes (1) to (6), if the trigger input cycle is shorter than the measurement cycle of the spectrometer, the input trigger is ignored. (7) External trigger signal output The start timing (pulse width: 1 μs) of integration can be output from the external trigger terminal (trigger output edge: rising or falling edge can be specified). (for rising edge) KACCC57EC 5

Evaluation software (accessory) By installing the evaluation software (SpecEvaluationUSB2.exe)* into a PC, you can perform the following basic operations. Acquire and save measured data Set measurement conditions Module information acquisition (wavelength conversion factor, mini-spectrometer type, etc.) Display graphs Arithmetic functions Pixel number to wavelength conversion Calculation in comparison with reference data (transmittance, reflectance) Dark subtraction Gaussian approximation (peak position and count, FWHM) Note: Up to eight mini-spectrometers can be connected to a single PC and used. *: Compatible OS Microsoft Windows 7 Professional SP1 (32-bit, 64-bit) Microsoft Windows Professional (32-bit, 64-bit) Microsoft Windows 1 Professional (32-bit, 64-bit) A DLL for controlling the hardware is available. Users can develop original measurement programs using the following development platform. Microsoft Visual Studio 2 (SP1) Visual C++ Microsoft Visual Studio 2 (SP1) Visual Basic Note: Microsoft, Windows, Visual Studio, Visual C++, and Visual Basic are either registered trademarks or trademarks of Microsoft Corporation in the United States and/or other countries. Dimensional outline (unit: mm) 1. 95. (4 ) M3 tap depth 6 6. 12..5 1.5 55. SMA connector Trigger connector Tolerance unless otherwise noted: ±.5 Weight: 95 g Micro USB KACCA414EA 6

Accessories USB cable Dedicated software (evaluation software, sample software, DLL) Options (sold separately) Input optical fiber Type no. Product name Core diameter (μm) A9763-1 6 Fiber for visible/near infrared range A9763-5 4 Specification NA=.22, length=1.5 m, low cost With SMA95D connector on each end NA=.22, length=1.5 m, small bending radius at fiber section With SMA95D connector on each end External trigger input coaxial cable A12763 Dimensional outline (unit: mm) 15 +5 BNC-J-17/U 1.5C-QEW MMCX-P-17B/U (4) KACCA35EA 7

lineup Type no. C12CA C12CAH C12MD C13CA C13CAH C13MD C11697MB C944CA C944CAH C945CB C11713CA C11714CB C1142GA C9913GC C9914GB C1111GA TM series TG series TG series Type TM-UV/VIS-CCD High sensitivity TM-UV/VIS-CCD TM-UV/VIS-MOS Wide dynamic range TM-VIS/NIR-CCD High sensitivity TM-VIS/NIR-CCD TM-VIS/NIR-MOS Wide dynamic range TM-VIS/NIR-MOS-II Trigger-compatible TG-UV-CCD High sensitivity TG-UV-CCD TG-SWNIR-CCD-II TG-RAMAN-I TG-RAMAN-II TG2-NIR Non-cooled type TG-cooled NIR-I Low noise (cooled type) TG-cooled NIR-II Low noise (cooled type) TG-cooled NIR-III Low noise (cooled type) Spectral response range (nm) 2 4 6 1 12 14 16 1 2 22 24 26 2 to 4 2 to 32 to 1 5 to 11 5 to 6 79 to 92 9 to 17 11 to 22 9 to 255 Spectral resolution max. (nm) 6 1* 3 1* 5 (λ=55 to 9 nm).3*.3* 7 7 2 Image sensor Back-thinned CCD 6 (λ=32 to 9 nm) Back-thinned CCD 1* (λ=32 to 9 nm) High-sensitivity CMOS linear Back-thinned CCD back-thinned CCD Back-thinned CCD back-thinned CCD InGaAs linear C1353MA C1354MA C14214MA C13555MA TF series TF-SWIR-MOS-II TF-RAMAN TF-RAMAN TF-VIS-MOS-II 5 to 11 79 to 92 79 to 15 34 to 3 3.5.4*.6 3 High-sensitivity C117MA C11MA * Typ. RC series RC-VIS-MOS Spectrometer module RC-SWNIR-MOS Spectrometer module 34 to 7 64 to 15 9 For installation into mobile measuring equipment Type no. C119MA C111MA RC series Type RC-VIS-MOS RC-SWNIR-MOS Spectral response range (nm) 2 4 6 1 12 14 16 1 2 22 24 26 34 to 7 64 to 15 Spectral resolution max. (nm) 9 Image sensor For installation into mobile measuring equipment (ultra-compact) Type no. C117MA C12666MA C12MA MS series Microspectrometer Type MS-SWNIR-MOS Spectral response range (nm) 2 4 6 1 12 14 16 1 2 22 24 26 34 to 7 34 to 5 64 to 15 Spectral resolution max. (nm) 2 15 15 Image sensor High-sensitivity

Related information www.hamamatsu.com/sp/ssd/doc_en.html Precautions Disclaimer s Technical information s Information described in this material is current as of July 21. Product specifications are subject to change without prior notice due to improvements or other reasons. This document has been carefully prepared and the information contained is believed to be accurate. In rare cases, however, there may be inaccuracies such as text errors. Before using these products, always contact us for the delivery specification sheet to check the latest specifications. The product warranty is valid for one year after delivery and is limited to product repair or replacement for defects discovered and reported to us within that one year period. However, even if within the warranty period we accept absolutely no liability for any loss caused by natural disasters or improper product use. Copying or reprinting the contents described in this material in whole or in part is prohibited without our prior permission. www.hamamatsu.com HAMAMATSU PHOTONICS K.K., Solid State Division 1126-1 Ichino-cho, Higashi-ku, Hamamatsu City, 435-55 Japan, Telephone: (1) 53-434-3311, Fax: (1) 53-434-514 U.S.A.: Hamamatsu Corporation: 36 Foothill Road, Bridgewater, N.J. 7, U.S.A., Telephone: (1) 9-231-96, Fax: (1) 9-231-121, E-mail: usa@hamamatsu.com Germany: Hamamatsu Photonics Deutschland GmbH: Arzbergerstr. 1, D-2211 Herrsching am Ammersee, Germany, Telephone: (49) 152-375-, Fax: (49) 152-265-, E-mail: info@hamamatsu.de France: Hamamatsu Photonics France S.A.R.L.: 19, Rue du Saule Trapu, Parc du Moulin de Massy, 912 Massy Cedex, France, Telephone: 33-(1) 69 53 71, Fax: 33-(1) 69 53 71 1, E-mail: infos@hamamatsu.fr United Kingdom: Hamamatsu Photonics UK Limited: 2 Howard Court, 1 Tewin Road, Welwyn Garden City, Hertfordshire AL7 1BW, United Kingdom, Telephone: (44) 177-294, Fax: (44) 177-325777, E-mail: info@hamamatsu.co.uk North Europe: Hamamatsu Photonics Norden AB: Torshamnsgatan 35 1644 Kista, Sweden, Telephone: (46)-59 31, Fax: (46)-59 31 1, E-mail: info@hamamatsu.se Italy: Hamamatsu Photonics Italia S.r.l.: Strada della Moia, 1 int. 6, 22 Arese (Milano), Italy, Telephone: (39)2-93 5 17 33, Fax: (39)2-93 5 17 41, E-mail: info@hamamatsu.it China: Hamamatsu Photonics (China) Co., Ltd.: B121, Jiaming Center, No.27 Dongsanhuan Beilu, Chaoyang District, Beijing 12, China, Telephone: (6) 1-656-66, Fax: (6) 1-656-266, E-mail: hpc@hamamatsu.com.cn Taiwan: Hamamatsu Photonics Taiwan Co., Ltd.: F-3, No. 15, Section2, Gongdao 5th Road, East District, Hsinchu, 3, Taiwan R.O.C. Telephone: (6)3-659-, Fax: (6)3-659-1, E-mail: info@hamamatsu.com.tw Cat. No. KACC1263E2 Jul. 21 DN 9