Total Carbon Column Observing Network David Griffith, Justus Notholt & TCCON network partners
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1 Tota Carbon Comn Observing Network David Griffith, Jsts Nothot & TCCON network partners Strong Wennberg Wnch Toon Bmenstock, Hase Nothot, Detscher, Messerschmidt Kyro Sssman Morino, Uchino Griffith Detscher Macatangay Feist, Giebe demaziere Sherock Robinson Smae 1
2 TCCON: Remote sensing of tota comn CO 2, CH 4, N 2 O, CO Direct-sn soar absorption spectroscopy in the near IR Retrieve tota comn amonts Derive comn average dry air moe fractions (e.g. X CO2 ) Using comn O 2 as interna standard X CO2 =CO 2 /O 2 x Sateite TCCON FTIR In-Sit 2
3 Why TCCON? Tota comn measrements : Are ess ssceptibe to oca sorces and sinks than in sit Are ess sensitive to vertica transport Is sef: Do not aias dirna and seasona bondary ayer transport into the measred comn amont As a standaone network - mode comparisons For sateite vaidation Mst be: SCIAMACHY, GOSAT, OCO-2, CarbonSat accrate and precise traceabe to WMO moe fraction scaes 3
4 Sothern Hemisphere TCCON stations Darwin Woongong Lader 4
5 Weather station Darwin TCCON container Protective Dome Sntracker Brker IFS125 5
6 Brker IFS125 6
7 Near IR soar absorption spectrm overview InGaAs detector Si detector 7
8 Anaysis by spectrm fitting e.g cm -1 CO 2 band Spectrm: zdb scdcca.006 Fitted: 14/09/ :54 PM Measred Fitted Resida x co2 = 8.16E+21 (1.09E+20) SZA: Zobs:.03 8
9 Raw daiy comn measrements Woongong, cear sky day 8.6x10 21 Comn CO2 X CO Daiy ipp fits X CO2 = comn CO 2 /comno 2 x CO CO O Xco2 4.70x comn O2 1σ scatter ~ 0.2 ppm (0.05%) Airmass dependence ~ 2ppm (before correction) 06:00 09:00 12:00 15:00 18:00 Time of Day (UT+10) 9
10 Precision and accracy: CO 2 Precision achieved: <0.2 ppm 1-σ repeatabiity, singe measrements Accracy by comparison of TCCON tota comns with integrated aircraft in sit profies sing WMO-caibrated instrments eg. HIPPO, TWP-ICE, IMECC Extrapoated to top and bottom of the atmosphere 10
11 Vaidation reation to WMO scaes eg TWP-ICE Darwin 2006 CO 2 anayser on board 1Hz CO 2, 0.1ppm precision Integrate vertica profie Aso HIPPO, a species 0 Aircraft CO 2 Profie CO Pressre (mb) CO 2 vmr (µmo.mo -1 )
12 TCCON vaidation against aircraft profies CO 2 and CH 4 CO 2 (1σ 0.1%) CH 4 (1σ 0.2%) y=(0.989 ± 0.001)x Frther detai: Wnch, D., et a. (2010), Caibration of the Tota Carbon Comn Observing Network sing Aircraft Profie Data, Atmos. Meas. Techn., 3,
13 TCCON vaidation against aircraft profies CO and N 2 O CO (1σ 2%) N 2 O (1σ 0.4%) Frther detai: Wnch, D., et a. (2010), Caibration of the Tota Carbon Comn Observing Network sing Aircraft Profie Data, Atmos. Meas. Techn., 3,
14 Precision and accracy: CO 2 Precision achieved: <0.2 ppm 1-σ repeatabiity, singe measrements Accracy by comparison of TCCON tota comns with integrated aircraft in sit profies sing WMO-caibrated instrments eg. HIPPO, TWP-ICE, IMECC Extrapoated to top and bottom of the atmosphere Comparabiity achieved across the network ~ 0.4 ppm (1-σ) from aircraft fight comparisons < 1 ppm overa Measrements and anaysis are standardised to avoid bias Ongoing work to improve: Instrmentation, anaysis software, spectroscopy 14
15 TCCON data Park Fas (46 N) Darwin(12 S) Lader (45 S) CO 2 / ppm CH 4 / ppm CO 2 CH Year Year
16 TCCON data Park Fas (46 N) Darwin(12 S) Lader (45 S) 160 CO CO / ppb N 2 O / ppb N 2 O Year Year
17 Sateite vaidation: GOSAT GOSAT (Japan) Lanched Jan 2009 FTIR spectrometer, backscattered soar NIR CO 2, CH 4 anaysis Lanched Jan 2009 by JAXA, Japan 3 day repeat orbit Vaidation by TCCON overpasses Oct
18 GOSAT-TCCON comparison GOSAT anaysis by ACOS (Wnch et a., ACP 2011 sbmitted) CO O 2 / pressre: Bias: Derived from spectra 1.8%, corrected Spectroscopy Aeroso/scattering 18
19 GOSAT-TCCON comparison GOSAT anaysis by SRON (Btz et a., GRL 2011) CO 2 CH 4 GOSAT TCCON CO 2, CH Pressre from ECMWF Bias not corrected
20 TCCON-Mode comparisons eg. Sara Mikaof Fetcher (yesterday) More at 20
21 First TCCON CO 2 inversion F. Chevaier et a. GRL 2011 (sbmitted) Compares inversions from in sit fask network (n=579) and 14 TCCON stations (n=490) Anna increase (ppm yr -1 ) NH Seasona cyce a priori: Inversion: In sit TCCON Goba CO 2 srface fxes inferred from srface air-sampe measrements and from srface retrievas of the CO 2 tota comn F. Chevaier et a., GRL, sbmitted Oct
22 TCCON inversion Chevaier et a Continenta /regiona fxes 22
23 Thank yo Strong Wennberg Wnch Toon Bmenstock, Hase Nothot, Detscher, Messerschmidt Kyro Sssman Morino, Uchino Griffith Detscher Macatangay Feist, Giebe demaziere Sherock Robinson Smae 23
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